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This paper aims to investigate the influence of the regional business environment on local firm innovation, considering various dimensions such as administrative, financial and legal environments.

Multiple regression analysis is employed to analyze archival data for firms listed on Chinese stock markets.

We find that the optimizations of the administrative and financial environments positively affect firm innovation, whereas the legal environment does not exert a similar impact. Our analysis also reveals that the business environment’s optimization significantly influences innovation in firms that are small, non-state-owned and operating in high-tech industries. Furthermore, the business environment acts as a moderating variable in the relationship between firm innovation and firm value.

This study contributes to a more comprehensive understanding of institutional-level determinants of firm innovation, highlighting the nuances of the legal environment and the importance of context-specific analysis, especially in emerging markets like China.

Developing countries can significantly enhance firm innovation by improving the business environment, including the optimization of administrative and financial systems, reducing transaction costs and ensuring capital supply. Tailored legal frameworks and alternative institutional strategies may also be explored.

This study explicitly emphasizes the governmental role in promoting firm innovation, shedding light on policy formulation and strategic alignment with local administrative policies.

To the best of our knowledge, this paper is the first to explore the relationship between the business environment and firm innovation using World Bank indicators in an emerging market context, providing novel insights into the unique dynamics of legal, financial and administrative sub-environments.

This paper aims to study a new halogen-free fame-retardant curing agent 1-aminoethylidenediphosphonate (AAEDP).

The AAEDP was synthesized by phosphoric acid, acetonitrile and ammonia. The chemical structures of AAEDP were characterized by proton nuclear magnetic resonance, mass spectrometry and Fourier transform infrared spectrometer. Thermal gravimetric analysis (TGA) and scanning electron microscope (SEM) would study the thermal properties and the char residues of AAEDP/EP. The thermal stability, mechanical and flame properties and morphology for the char layer of composite materials were separately investigated using TGA, tensile and charpy impact tests, limiting oxygen index (LOI), UL-94 HB flammability standard (UL-94) and SEM.

The results showed that the AAEDP had been prepared successfully. When the intumescent flame retardant was added into the EP, the LOI of composite material was improved.

The AAEDP can be prepared successfully and can improve the flame resistance of composite material.

The AAEDP has excellent flame-retardant properties and produce no toxic fumes when burnt in case of fire.

The results showed that the phosphorus content of AAEDP was 2.958 Wt.%; the impact and tensile strength of the composite material were 6.417 kJ m⁻² and 38.0 MPa, respectively; and the LOI and UL-94 were 29.7% and V-0 ranking, respectively. The TGA results indicated that the carbon residue ratio can be increased by 1000°C in air. The denser and more uniform structure of residual carbon prevents heat transfer and diffusion, restricts the production of combustible gas and reduces the rate of heat release.

With the development of 3D printing or additive manufacturing (AM), curved layer fused deposition modeling (CLFDM) has been researched to cope with the flat layer AM inherited problems, such as stair-step error, anisotropy and the time-cost and material-cost problems from the supporting structures. As one type of CLFDM, cylindrical slicing has obtained some research attention. However, it can only deal with rotationally symmetrical parts with a circular slicing layer, limiting its application. This paper aims to propose a ray-based slicing method to increase the inter-layer strength of flat layer-based AM parts to deal with more general revolving parts.

Specifically, the detailed algorithm and implementation steps are given with several examples to enable readers to understand it better. The combination of ray-based slicing and helical path planning has been proposed to consider the nonuniform path spacing between the adjacent paths in the same curved layer. A brief introduction of the printing system is given, mainly including a 3D printer and the graphical user interface.

The preliminary experiments are successfully conducted to verify the feasibility and versatility of the proposed and improved slicing method for the revolving thin-wall parts based on a rotary 3D printer.

This research is early-stage work, and the authors are intended to explore the process and show the initial feasibility of ray-based slicing for revolving thin-wall parts using a rotary 3D printer. In general, this research provides a novel and feasible slicing method for multiaxis rotary 3D printers, making manufacturing revolving thin-wall and complex parts possible.

The purpose of this paper is to separate and purify flavonoids from glycyrrhiza by macroporous adsorption resin (MAR) mixed-bed technology.

The adsorption performance of MAR and MAR mixed bed for flavonoids was studied using ultraviolet-visible spectrophotometry.

The research shows that the MAR mixed bed of LZ-50+LZ-59 with a mass ratio of LZ-50:LZ-59(m:m) = 1:1 was the optimized combination with the optimal conditions of adsorption (pH = 6, T = 45°C) and desorption (liquid ratio R = 70%, T = 50°C, pH = 8) obtained, relatively.

This paper provides a novel way to separate flavonoids from glycyrrhiza. Under the optimal conditions, the adsorption rate (F) of MAR mixed-bed LZ-50+LZ-59 to the flavonoids was 62.5 per cent/g, the desorption rate (D) was 89.23 per cent and the purity was achieved at 80 per cent.

This paper aims to study a new halogen-free flame retardant that was prepared and characterised.

The phenyl phosphinic arid di-4-[1-(4-pheny phodphonic acid monophenyl ester-yl)-methyl-ethyl] phenyester dimelaminium (PDEPDM) was synthesised using phenylphosphonic dichloride, melamine, bisphenol A, triethylamine and dichloromethane via solvent-based reaction, that was added into the polyethylene to test flame performance. The chemical structures of PDEPDM were characterised by ¹H nuclear magnetic resonance spectroscopy, mass spectrometry and Fourier transform infrared spectrometer. The thermal stability, mechanical and flame properties, and morphology for the char layer of composite materials were separately investigated using thermogravimetric analysis, tensile and charpy impact tests, limiting oxygen index (LOI) and UL-94 HB flammability standard and scanning electron microscope.

The results showed that the PDEPDM had been prepared successfully. When the intumescent fame retardant was added into the PE, the LOI of composite material was improved.

The PDEPDM can be prepared successfully and can improve the flame resistance of composite material.

The PDEPDM has excellent flame-retardant properties and produce no toxic fumes when burnt in case of fire.

Under the optimal conditions, when the 32 per cent (Wt.%) PDEPDM was added into the PE, the LOI was 29.8, tensile strength and impact strength were 10.06 MPa and 16.77 kJ/m².

The purpose of this paper is to discriminate fake interference caused by polygonal approximation so as to achieve accurate assembly sequence planning and assembly simulation.

An approximation zone model is proposed to formulate polygonal approximation. Fake interference is discriminated from hard interference by evaluating if polygonal models intersect within corresponding approximation zones. To reduce the computation, the surface-surface, surface-end face and end face-end face intersection test methods have been developed to evaluate the intersection and obtain collision data. An updated collision detection algorithm with this method is presented, which is implemented by a system named AutoAssem.

This method has been applied to a set of products such as a valve for assembly interference matrix generation, static and dynamic collision detection. The results show that it ensures the accuracy of assembly sequence planning and assembly simulation for polygonal models.

This method facilitates assembly design in the virtual environment with polygonal models. It can also be applied to computer aided design systems to achieve quick and accurate collision detection.

Fake interference between polygonal models may result in serious errors in assembly sequence planning and assembly simulation. Assembly zone model and novel polygon intersection verification methods have been proposed to effectively tackle this problem. Compared to current methods, this method considers valid penetration direction and approximation difference, does not need to process complicated auxiliary data and can be easily integrated with current collision detection methods.

The purpose of this paper is to prepare a higher chloromethylation degree (CD) modified macroporous adsorption resin (MAR, LX1180-Cl) and further study their adsorption performance.

CD and crosslinking degree were evaluated using stationary potential step and rotating-disk method, the adsorption performance of LX1180-Cl and LX1180 for flavonoids were studied using the UV-VIS spectrophotometry.

This research realized high CD (9.6 mass %) on high crosslinking MAR, LX1180. In tandem, the adsorption performance of them to flavonoids finds that the matching degree of polarity (presented with CD) and size were the critical factor to adsorption. It was also found that the reaction time had reduced to 24 h with the addition of iron particles into the zinc chloride (ZnCl₂) catalyst.

The study on reaction mechanism and the function principle of hybrid catalyst were speculated, but not the rigid experimental result.

This contribution can provide a rule for the separation and purification of natural products with the aim to improve food additive removal or isolation and purification of flavonoids used for healthcare applications.

This contribution provided a novel way to obtain high degree of CD with high crosslinking MAR, CD of commercially available MAR was improved by 2.5 times to 9.6 percent under crosslinking degree at 58.2 percent, compared with reported CD value (ca. 4.2 percent under crosslinking degree at 20.0 percent), which will be useful in the following further systematically research about the adsorption and separation selectivity of MAR. Besides, the primitive chosen principle of MAR according to the substrate was also presented. Moreover, the chloromethylation mechanism, although speculative, was briefly presented, which will stimulate the related study.

Achieving sustainable development in terms of people, prosperity and partnership is the main aspect in any country’s plan for development. This sustainable development has to be achieved in three major dimensions, that is, economic, social and environmental in an integrated, balanced and systematic way. The same is highlighted in the United Nations’ (UN) vision for sustainable development by 2030. The purpose of this study is to identify the critical barriers of urban sustainability and gender equality with reference to Indian context, to suggest the strategies to achieve sustainable development in the referred area and to evaluate the relationship between them.

The major contribution of this study lies in the development of a contextual relationship model from the various identified critical barriers in Indian context, using interpretive structural modeling with MICMAC analysis.

Of the 17 goals given by UN, considering the Indian context, the goals of building resilient infrastructure, promoting inclusive and sustainable industrialization and fostering innovation; promoting sustained and inclusive economic growth along with full and productive employment and decent work for all; and gender equality and empowering women at all levels seem to be the major challenges and the same are selected in this study for further analysis. To understand the major challenges in these areas and also to find the way forward, the study has set following three major objectives: to identify the critical barriers of urban sustainability and gender equality with reference to Indian context; to suggest the strategies to achieve sustainable development in the referred area; and to evaluate the relationship between them.

Considering the highly volatile and complex demand requirements, this approach may help to enable the government to tackle issues/challenges related to both urban sustainability and gender inequality on priority basis and in a holistic manner to achieve the goals of sustainable development, thereby improving the quality of life.