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It is observed that many destinations are implementing sport tourism offerings to enhance their ability to attract visitors through satisfying their desires of new experiences. This has led to a highly competitive sport tourism market and as a result destinations engage in various marketing techniques and promotional tools to gain an advantage. For that reason this research was undertaken to acquire a greater understanding of the importance of promotional tools to successfully and efficiently market sport tourism experiences.

The construct of this study comprises of two stages. The aim of the first stage is to evaluate the specific tools used to promote sport tourism and sport tourism experiences in Barbados by examining the responses of various sporting and tourism bodies. The second stage of this research was conducted to present and analyze how marketing/promotional tools could contribute to better market sport tourism experiences.

The research found that many of the promotional tools implemented in Barbados during their marketing process correspond with those used internationally. However, problems of poor and insufficient sporting facilities as well as little collaboration between tourism and sporting entities, hamper the success of Barbados as a sport tourism destination. This further minimized Barbados’ ability to market favorable tourism experiences. This therefore shows that while promotional tools are essential in attracting tourists, other elements must also be taken into consideration to ensure sport tourists have positive experiences which would lead to a successful sport tourism destination.

Few studies in this area have been undertaken in the Caribbean. This study attempts to fill this gap by examining the implementation of sport tourism offerings to attract visitors to Barbados.

This paper reviews the range of sensors used in electronic nose (e‐nose) systems to date. It outlines the operating principles and fabrication methods of each sensor type as well as the applications in which the different sensors have been utilised. It also outlines the advantages and disadvantages of each sensor for application in a cost‐effective low‐power handheld e‐nose system.

This paper aims to reveal the tribochemical reaction mechanism on the nano-cutting interface between HMX crystal and diamond tool.

Molecular dynamics simulation of HMX crystal nano-cutting by the reactive force field is carried out in this paper. The affinity of activated atoms and friction damage at the different interface have been well identified by comparing two cutting systems with diamond tool or indenter. The analyses of reaction kinetics, decomposition products and reaction pathways are performed to reveal the underlying atomistic origins of tribocatalytic reaction on the nano-cutting interface.

The HMX crystals only undergo damage and removal in the indenter cutting, while they appear to accelerate thermal decomposition in the diamond cutting. the C-O affinity is proved to be the intrinsic reason of the tribocatalytic reaction of the HMX-diamond cutting system. The reaction activation energy of the HMX crystals in the diamond cutting system is lower, resulting in a rapid increase in the decomposition degree. The free O atoms can induce the asymmetric ring-opening mode and change the decomposition pathways, which is the underlying atomistic origins of the thermal stability of the HMX-diamond cutting system.

This paper describes a method for analyzing the tribochemical behavior of HMX and diamond, which is beneficial to study the thermal stability in the nano-cutting of HMX.

Proper selection of the stability parameter determines the accuracy of dendrite tip kinetics at a single crystal scale. Recently developed sophisticated phase field modelling of a single grain evolution provides evidence that this parameter is not constant during the process. Nevertheless, in the commonly used micro-macroscopic simulations of alloy solidification, it is a common practice to use a constant value of the stability parameter, resulting from the marginal stability theory. This paper aims to address the issue of how this inaccuracy in modelling crystal growth kinetics can influence numerically predicted zones of columnar and equiaxed dendrites and the macro-segregation formation.

Using the original authors’ micro-macroscopic computer simulation model of binary alloy solidification, the calculations have been performed for the Kurz-Giovanola-Trivedi (KGT) crystal growth kinetics with two different values of the stability parameter, and for two different compositions of Al-Cu alloys. The computational model is based on single domain-based formulation of transport equations, which are discretized on control-volume mesh. To identify zones of different grain structures, developing within the two-phase liquid-solid region, an envelope of columnar dendrite tips is tracked on a fixed non-orthogonal, triangular control volume grid. The models of porous and slurry media are used, along with the concept of the switching function, to account for diverse flow resistances in the columnar and equiaxed crystal zones. The numerical predictions are carefully studied to address the question of how the chosen stability parameter influences macroscopic structures of a cast, the most important issue from the engineering point of view.

The carried-out comprehensive numerical analysis shows that the value of the stability parameter of the KGT-constrained dendrite growth model does not have a direct significant impact on the macrosegregation formation. It, however, visibly influences the undercooling along the front, separating different dendritic structures and the size of the undercooled melt region where the equiaxed grains can develop. It also affects the amount of eutectic phase created.

To the best of the authors’ knowledge, this is the first attempt at estimating the influence of some inaccuracies, caused by possible ambiguities in choosing the stability constant of the KGT law, on numerically predicted macroscopic fields of solute concentration, the developing zones of columnar and equiaxed crystals and the macrosegregation patterns.

A finite element method for the analysis of combined radiative and conductive heat transport in a finite axisymmetric configuration is presented. The appropriate integro‐differential governing equations for a grey and non‐scattering medium with grey and diffuse walls are developed and solved for several model problems. We consider axisymmetric, cylindrical geometries with top and bottom boundaries of arbitrary convex shape. The method is accurate for media of any optical thickness and is capable of handling a wide array of axisymmetric geometries and boundary conditions. Several techniques are presented to reduce computational overhead, such as employing a Swartz‐Wendroff approximation and cut‐off criteria for evaluating radiation integrals. The method is successfully tested against several cases from the literature and is applied to some additional example problems to demonstrate its versatility. Solution of a free‐boundary, combined‐mode heat transfer problem representing the solidification of a semitransparent material, the Bridgman growth of an yttrium aluminium garnet (YAG) crystal, demonstrates the utility of this method for analysis of a complex materials processing system. The method is suitable for application to other research areas, such as the study of glass processing and the design of combustion furnace systems.

The aim of this paper is to provide an easy method of extrusion freeforming to fabricate microwave electromagnetic bandgap (EBG) crystals. EBG crystals are periodic dielectric structures that can block wave propagation and generate a bandgap. These crystals can be used in high capability antennae, electromagnetic wave semiconductors, microresonators, high‐reflectivity mirrors and polarizing beam splitters.

The effects of extrusion process parameters and paste characteristics were investigated. Finally, one‐period and two‐period woodpile EBG crystals with bandgaps in the frequency region of 90‐110 GHz were fabricated and the bandgap was measured.

The filament diameter is influenced by whether extrusion is carried out with or without a substrate and by the free fall‐distance from the nozzle. The quality of lattice structures is dependent on paste flow and properties. A ceramic paste with 60 vol. % (the fraction of ceramic powder based on solvent‐free polymer) was well suited to fabrication. The solvent content also influenced the fabrication. The experimental results show that under ∼12 per cent solvent mass fraction in the paste and relatively high extrusion ram velocity (more than 0.014 mm/s) at a pressure of 14 MPa, samples with high quality were fabricated.

This paper demonstrates that the rapid prototyping method of extrusion freeforming can be applied for the fabrication of EBG crystals from ceramic powders and the important factors which influence the product quality are identified.

This paper aims to study the microstructural hot corrosion behaviour of the sintered Y₂SiO₅ ceramic silicate under a Na₂SO₄ + V₂O₅ mixture at an engine representative temperature of 1150°C. Y₂SiO₅ is a promising candidate for thermal barrier coatings (TBC) due to its excellent chemical stability at high temperatures. As a continuous source of Y₃+, it is expected that Y₂SiO₅ environmental barrier coating may prolong the lifetime of TBC systems by stopping the degradation caused by the loss of the Y₂O₃ stabilizer.

Two routes were chosen for the yttria silicate powder synthesis by sol-gel from TEOS and APTES precursors as the difference in Si source changed the ratio of Y₂SiO₅/Y₂Si₂O₇ phases. Hot corrosion studies using Na₂SO₄ and V₂O₅ mixtures were conducted on both surfaces of APTES and TEOS tablets at 1150°C for 8 h in atmospheric air. The morphology and microstructure analyses of the silicate samples after hot corrosion tests were carried out using a SEM and X-ray diffraction analyse techniques.

Based on the degradation, the general status of the APTES tablet after hot corrosion presents a better hot corrosion resistance at a temperature of 1150°C than does that of the TEOS tablet. In the TEOS tablet, the crystal morphology of NaY9Si60O26 woodchip shapes with a size of 60 µm is developed on the surface for finally initiating some cracks. In the APTES case, the crystal morphology of rod-like shapes with a size of 100 µm is developed; hence, a dense thick layer predominately postpones the reaction of V₂O₅ and Na₂SO₄ with yttria silicate, and consequently, less damage is observed.

Coating yttria silicate preparation is very complicated; the problems of a high synthesis temperature, long production period and low yield still need to be solved. Under these perspectives, ceramics prepared via spark plasma sintering (SPS) can reach theoretical high densities and a fine grain size can be retained after the SPS process; hence, well resistance to the corrosion in molten salts is expected to obtain for the sintered yttria silicate tablets.