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Article
Publication date: 26 September 2022

Amirul Syafiq, Nasrudin Abd. Rahim, Vengadaesvaran Balakrishnan and A.K. Pandey

This paper introduced the simple synthesis process of self-cleaning coating with fog-resistance property using hydrophobic polydimethylsiloxane (PDMS) polymer and nano-calcium…

Abstract

Purpose

This paper introduced the simple synthesis process of self-cleaning coating with fog-resistance property using hydrophobic polydimethylsiloxane (PDMS) polymer and nano-calcium carbonate (nano-CaCO3) and titanium dioxide (TiO2).

Design/methodology/approach

The synthesis method of PDMS/nano-CaCO3-TiO2 is based on sol-gel process. The crosslinking between PDMS and nanoparticles is driven by the covalent bond at temperature of 50°C. The 3-Aminopropyltriethoxysilane is used as binder for nanoparticles attachment in polymer matrix. Two fabrication methods are used, which are dip- and spray-coating methods.

Findings

The prepared coated glass fulfilled the requirement of standard self-cleaning and fog-resistance performance. For the self-cleaning test BS EN 1096-5:2016, the coated glasses exhibited the dust haze value around 20%–25% at tilt angle of 10°. For the antifog test, the coated glasses showed the fog haze value were below 2% and the gloss value were above 85%. The obtained results completely achieved the standard antifog value ASTM F659-06 protocol.

Research limitations/implications

Findings will provide an infrastructure support for the building glass to enhance building’s energy efficiency, cleaning performance and friendly environment.

Practical implications

This study proposed the simple synthesis method using hydrophobic polymer and nano-CaCO3 and nano-TiO2, which can achieve optimum self-cleaning property at low tilt angle and fog-resistance performance for building glass.

Social implications

The research findings have high potential for building company, cleaning building company and government sector. The proposed project capable to reduces the energy consumption about 20% per annum due to labor cost, time-consuming and safety during manual cleaning.

Originality/value

The novel method to develop self-cleaning coating with fog-resistance using simple synthesis process and fabrication method for building glass application.

Open Access
Article
Publication date: 15 May 2020

Muhammad Amirul Syafiq Hamsan and Muhammad Zahir Ramli

Pahang beaches draw more than thousand visitors throughout the year. From the year 2006 to 2018, more than 30 drowning and near-drowning cases were recorded mainly from rip…

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Abstract

Purpose

Pahang beaches draw more than thousand visitors throughout the year. From the year 2006 to 2018, more than 30 drowning and near-drowning cases were recorded mainly from rip currents. Rip currents are defined as unexpected currents that carried beachgoers away to seaward direction more than approximately 50 m from shore. The prediction of rip current development is very important for the protection of human life. This study aims to conduct preliminary survey and field works to identify rip current hazards.

Design/methodology/approach

The output would be an early warning preventative mitigation to public in Pahang. Beach state model, dimensionless fall velocity, littoral environment observation and relative tidal range were recorded for five recreational beaches during two different months (March and April 2018). The morphodynamic parameters such sediment fall velocity, sediment grain size and beach slope are then analysed using software PROFILER. Classification of risks was done based on beach morphodynamic model. The morphodynamics are classified as low tide bar rip, barred and low tide terrace associated with rip current, bar dissipative, reflective, non-bar dissipative, low tide terrace and ultra-dissipative.

Findings

Result shows three out of five recreational beaches may develop high-risk rip currents. During the first month of the survey, Batu Hitam (BH) was recorded the only one recreational beach that may develop high-risk rip current followed by Teluk Cempedak (TC) and Kempadang (KEM) as middle-risk rip current beaches, while Balok (BA) and Sepat (SEP) as low-risk rip current beaches. Different during second month of the survey, BA, BH and SEP were recorded as high-risk rip current beaches while TC and KEM as low-risk rip current beaches.

Originality/value

The results are consistent with beach incidents (drowning and near-drowning) reported.

Details

Ecofeminism and Climate Change, vol. 1 no. 1
Type: Research Article
ISSN: 2633-4062

Keywords

Article
Publication date: 18 January 2023

Amirul Syafiq, Farah Khaleda Mohd Zaini, Vengadaesvaran Balakrishnan and Nasrudin Abd. Rahim

The purpose of this paper is to introduce the simple synthesis process of thermal-insulation coating by using three different nanoparticles, namely, nano-zinc oxide (ZnO)…

Abstract

Purpose

The purpose of this paper is to introduce the simple synthesis process of thermal-insulation coating by using three different nanoparticles, namely, nano-zinc oxide (ZnO), nano-tin dioxide (SnO2) and nano-titanium dioxide (TiO2), which can reduce the temperature of solar cells.

Design/methodology/approach

The thermal-insulation coating is designed using sol-gel process. The aminopropyltriethoxysilane/methyltrimethoxysilane binder system improves the cross-linking between the hydroxyl groups, -OH of nanoparticles. The isopropyl alcohol is used as a solvent medium. The fabrication method is a dip-coating method.

Findings

The prepared S1B1 coating (20 Wt.% of SnO2) exhibits high transparency and great thermal insulation property where the surface temperature of solar cells has been reduced by 13°C under 1,000 W/m2 irradiation after 1 h. Meanwhile, the Z1B2 coating (20 Wt.% of ZnO) reduced the temperature of solar cells by 7°C. On the other hand, the embedded nanoparticles have improved the fill factor of solar cells by 0.2 or 33.33%.

Research limitations/implications

Findings provide a significant method for the development of thermal-insulation coating by a simple synthesis process and low-cost materials.

Practical implications

The thermal-insulation coating is proposed to prevent exterior heat energy to the inside solar panel glass. At the same time, it can prevent excessive heating on the solar cell’s surface, later improves the efficiency of solar cell.

Originality/value

This study presents a the novel method to develop and compare the thermal-insulation coating by using various nanoparticles, namely, nano-TiO2, nano-SnO2 and nano-ZnO at different weight percentage.

Details

Pigment & Resin Technology, vol. 53 no. 4
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 30 September 2022

Amirul Syafiq, Vengadaesvaran Balakrishnan and Nasrudin Abd. Rahim

This paper aims to design the nano-titanium dioxide (TiO2) coating system which has superhydrophilic property, self-cleaning mechanism and antifog property as well as strong…

Abstract

Purpose

This paper aims to design the nano-titanium dioxide (TiO2) coating system which has superhydrophilic property, self-cleaning mechanism and antifog property as well as strong adhesion on glass substrate.

Design/methodology/approach

Two hydrophilic materials have been used such as TiO2 nanoparticles as fillers and hydrophilic copolymer, Pluronic F-127 by using simple sol–gel approach. The prepared solution was applied onto glass through dip- and spray-coating techniques and then left for drying at ambient temperature.

Findings

The nano-TiO2 superhydrophilic coating has achieved the water contact angle of 4.9° ± 0.5°. The superhydrophilic coating showed great self-cleaning effect against concentrated syrup and methylene blue where thin layer of water washes the dirt contaminants away. The nano-TiO2 coating exhibits great antifog performance that maintains high transparency of around 89% when the coated glass is placed above hot-fog vapor for 10 min. The fog droplets were condensed into water film which allowed the transmission of light through the glass. The strong adhesion of coated glass shows no total failure at scratch profile when impacted with scratch load of 500, 800 and 1,200 mN.

Research limitations/implications

Findings will be useful in the development of self-cleaning superhydrophilic coating that is applicable on building glass and photovoltaic panel.

Practical implications

The developed nano-TiO2 coating is developed by the combination of hydrophilic organic copolymer–inorganic TiO2 network to achieve great superhydrophilic property, optimum self-cleaning ability and supreme antifog performance.

Social implications

The findings will be useful for residents in building glass window where the application will reduce dust accumulation and keep the glass clean for longer period.

Originality/value

The synthesis of nano-TiO2 superhydrophilic coating which can be sprayed on large glass panel and cured at ambient temperature.

Article
Publication date: 2 February 2024

Reasmy Raj, Amirul Syafiq, Vengadaesvaran Balakrishnan, Shakeel Ahmad, Nasrudin Abd Rahim, Pouya Hassandarvish, Sazaly Abu Bakar and A.K. Pandey

This paper aims to fabricate a polymer-based polyethylene glycol (PEG) coating with acrylic resin as a binder that can show antiviral activity against the feline coronavirus…

Abstract

Purpose

This paper aims to fabricate a polymer-based polyethylene glycol (PEG) coating with acrylic resin as a binder that can show antiviral activity against the feline coronavirus (FCov) on the glass substrate.

Design/methodology/approach

The PEG/acrylic coating systems of different weight percentages were coated on the glass substrates using the spray-coating method and cured at room temperature for 24 h.

Findings

The coating system containing 20 Wt.% of PEG exhibits the highest antiviral activities as high as 99.9% against FCov compared with other samples.

Research limitations/implications

Findings will be useful in the development of antiviral coating for PPE fabrics by using the simple synthesis method.

Originality/value

Application of PEG as an antiviral agent in the antiviral coating system with high antiviral activities about 99.9%.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 22 November 2023

Khishn Kumar Kandiah, Vengadaesvaran Balakrishnan, Amirul Syafiq, Nasrudin Abd Rahim, Adarsh Kumar Pandey, Yee Seng Tan, Sanjay J Dhoble, Ramesh Kasi and Ramesh Subramaniam

There is a strong inducement to develop new inorganic materials to substitute the current industrial pigments, which are known for their poor ultraviolet absorbent and low…

Abstract

Purpose

There is a strong inducement to develop new inorganic materials to substitute the current industrial pigments, which are known for their poor ultraviolet absorbent and low photoluminescence (PL) properties. The purpose of this paper is to invent a better rare-earth-based pigment material as a spectral modifier with good luminescence properties to enhance the spectral response for photovoltaic panel application.

Design/methodology/approach

Different phosphor samples made of nano-calcium carbonate (CaCO3) with varied wt.% of the dopant Dysprosium doped calcium borophosphate (CBP/Dy) as (W0 – 0%, W1 – 3,85%, W2 – 7.41%, W3 –10.71% and W4 –13.79%) were prepared via the solid-state diffusion method at 600 °C for 6 h using a muffle furnace. The structural, morphological and luminescence properties of the CaCO3:CBP/Dy powder samples were examined using scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and PL test.

Findings

The XRD, SEM and FTIR results verified the crystalline formation, morphological behaviour and vibration bonds of synthesized CBP/Dy-doped CaCO3 powder samples. XRD pattern revealed that the synthesized powder samples exhibit crystalline structured materials, and SEM results showed irregular shape and porous-like structured morphologies. FTIR spectrum shows prominent bands at 712, 874 and 1,404 cm−1, corresponding to asymmetric stretching vibrations of CO32− groups and out-of-plane bending. PL characterization of CBP/Dy-doped CaCO3 (sample W) shows emission at 427 nm (λmax) under the excitation of 358 nm. The intensity of PL emission spectra drops due to the concentration quenching effect, while the maximum PL intensity is observed in the W3 phosphor powder system.

Research limitations/implications

This phosphor powder is expected to find out the potential application such as a spectral modifier which is applied to match the energy of photons with solar cell bandgap to improve spectral absorption and lead to better efficiency.

Originality/value

The introduction of a nano-CaCO3:CBP/Dy hybrid powder system with good luminescence properties to be used as spectral modifiers for solar cell application has been synthesized in the lab, which is a novel attempt.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 13 September 2023

Amirul Syafiq, Lilik Jamilatul Awalin, Syukri Ali and Mohd Arif

The paper aims to design the optimum formulation of the nano-titanium dioxide (TiO2) hydrophilic coating system using the synthetic polypropylene glycol (PPG), which can create…

Abstract

Purpose

The paper aims to design the optimum formulation of the nano-titanium dioxide (TiO2) hydrophilic coating system using the synthetic polypropylene glycol (PPG), which can create the reflection and absorption property.

Design/methodology/approach

TiO2 nanoparticles are used as fillers, and PPG has been blended at the proper ratio of 1PPG: 0.2TiO2. The prepared resin has been applied onto the glass substrate at different numbers of glass immersions during the dip-coating fabrication process. One-time glass immersion is labeled as T1 coating, two-time glass immersion is labeled as T2 coating and three-time glass immersion is labeled as T3 coating. All the prepared coating systems were left dry at ambient temperature.

Findings

T3 coating showed the lowest reading of WCA value at 40.50°, due to higher surface energy at 61.73 mN/m. The T3 coating also shows the greatest absorbance property among the prepared coating systems among the prepared coating. In terms of reflectance property, the T2 coating system has great reflectance in UV region and near-infrared region, which is 16.47% and 2.77 and 2.73%, respectively. The T2 coating also has great optical transmission about 75.00% at the visible region.

Research limitations/implications

The development of thermal insulation coating by studying the relationship between convection heat and reflectance at different wavelengths of incident light.

Practical implications

The developed coating shows high potential for glass window application.

Originality/value

The application of the hydrophilic coating on light absorption, reflectance and transmission at different wavelengths.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

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